787-70-2

  • Product Name:Biphenyl-4,4'-dicarboxylic acid
  • Molecular Formula:C14H10O4
  • Purity:99%
  • Molecular Weight:242.231
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Product Details;

CasNo: 787-70-2

Molecular Formula: C14H10O4

Appearance: White to light beige powder

Fast Delivery Biphenyl-4,4'-dicarboxylic acid 787-70-2 In Medicine with Best Price

  • Molecular Formula:C14H10O4
  • Molecular Weight:242.231
  • Appearance/Colour:White to light beige powder 
  • Melting Point:>300 °C(lit.) 
  • Boiling Point:482.5 °C at 760 mmHg 
  • PKA:3.77±0.10(Predicted) 
  • Flash Point:259.7 °C 
  • PSA:74.60000 
  • Density:1.347 g/cm3 
  • LogP:2.75000 

Biphenyl-4,4'-dicarboxylic acid (Cas 787-70-2) Usage

Biphenyl-4,4'-dicarboxylic acid (H2bpdc) is a bridging ligand used in the synthesis of a novel metal-organic framework compound, denoted as [Cu2(bpdc)2(Dpq)2(H2O)]·H2O (1). This complex has been prepared through a hydrothermal reaction involving copper chloride and a combination of ligands, including biphenyl-4,4'-dicarboxylic acid (H2bpdc) and dipyrido[3,2-d:2',3'-f]quinoxaline (Dpq).

787-70-2 Relevant articles

Controlling interpenetration for tuning porosity and luminescence properties of flexible MOFs based on biphenyl-4,4′-dicarboxylic acid

Belén Fernández,a   Garikoitz Beobide,b   Ignacio Sánchez,a   Francisco Carrasco-Marín,a   José M. Seco,c   Antonio J. Calahorro,a   Javier Cepeda*cd  and  Antonio Rodríguez-Diéguez*a

, CrystEngComm, Issue 8, 2016

A careful computational analysis on the crystal structures permits unravelling their void systems. Moreover, characterising the photoluminescence emission of the compounds at variable excitation wavelengths provides an opportunity to couple the luminescence response with their porosity, which could signify the potential utility of these materials as photofluorescent sensors for small adsorbates.

Acceptorless dehydrogenation of primary alcohols to carboxylic acids by self-supported NHC-Ru single-site catalysts

Yin, Shenxiang,Zheng, Qingshu,Chen, Jie,Tu, Tao

, p. 165 - 172 (2022/03/23)

The acceptorless dehydrogenation of dive...

Electrochemical coupling halobenzene into biphenyl on a reusable Pd nanoparticle-coated carbon-paper electrode at ambient conditions

Wang, Chao-Nan,Lu, Yong-Heng,Liu, Yue,Liu, Jun,Yang, Yao-Yue,Zhao, Zhi-Gang

, p. 3997 - 4003 (2021/03/06)

Electrochemical organic synthesis (EOS) ...

Cobalt-catalyzed cross-coupling reactions of aryl- And alkylaluminum derivatives with (hetero)aryl and alkyl bromides

Dilauro, Giuseppe,Messa, Francesco,Bona, Fabio,Perrone, Serena,Salomone, Antonio

supporting information, p. 10564 - 10567 (2021/10/19)

A simple cobalt complex, such as Co(phen...

787-70-2 Process route

1,1’-(biphenyl-4,4’diyl)bis(2-chloroethanone)
24860-53-5

1,1’-(biphenyl-4,4’diyl)bis(2-chloroethanone)

terephthalic acid
100-21-0

terephthalic acid

4,4'-diphenic acid
787-70-2

4,4'-diphenic acid

Conditions
Conditions Yield
 
 
para-xylene
106-42-3

para-xylene

terephthalic acid
100-21-0

terephthalic acid

4,4'-benzophenonedicarboxylic acid
964-68-1

4,4'-benzophenonedicarboxylic acid

fluorenone-2-carboxylic acid
784-50-9

fluorenone-2-carboxylic acid

p-Toluic acid
99-94-5

p-Toluic acid

4,4'-diphenic acid
787-70-2

4,4'-diphenic acid

benzoic acid
65-85-0,8013-63-6

benzoic acid

Conditions
Conditions Yield
With oxygen; acetic acid; hydrogen bromide; cobalt(II) acetate; manganese(II) acetate; In water; at 160.3 - 161.2 ℃; for 8h; under 4650.47 Torr; Product distribution / selectivity; Pilot scale;
 
With oxygen; acetic acid; hydrogen bromide; cobalt(II) acetate; manganese(II) acetate; In water; at 160.3 - 161.2 ℃; for 8h; under 4650.47 Torr; Product distribution / selectivity; Pilot scale;
 

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